New Machine Produces Usable Gasoline from Air...

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lxskllr

No Lifer
Nov 30, 2004
59,238
9,744
126
I think it would be hard to get gasoline under $4/gallon; I seem to recall an estimate of $10/gallon.
The figure in my head is $5/G for mid-high grade. There's the corn free benefit, the higher octane premium, and a bit of money for being "eco". Details matter though, and I have no idea what this machine costs, and what the fuel's like. If it's especially pure like alkylate fuel, I'd pay significantly more.
 

dullard

Elite Member
May 21, 2001
25,825
4,385
126
Finally, I expect they'd use the Fischer-Tropsch process to turn it into gasoline.
Most likely, yes. As something totally off topic, I have seen the outside of this plant in person. And I have acquaintances who have worked there converting coal into diesel. https://en.wikipedia.org/wiki/Fischer–Tropsch_process#/media/File:Sasol_Secunda_19.jpg

Potholes big enough to swallow your vehicle when driving the main highway to Secunda. Also, that plant is supposedly the world's largest CO2 emitter.
 

Josh128

Senior member
Oct 14, 2022
942
1,423
106
Most of this is well-understood. It appears to start with a dehumidifier to get water out of the air. (There are a few methods, thermal or chemical; I'm not sure which they use.) Then I expect they'd use electrolysis to extract hydrogen from the water. Finally, I expect they'd use the Fischer-Tropsch process to turn it into gasoline.

The missing part of this is extracting the other ingredient in Fischer-Tropsch, CO2, from air. How it works, I don't know. Does it integrate with the dehumidifier?


You're right about energy storage, wrong about the method. Hydrogen is easier to make than methane, and a fuel cell is more efficient than burning. Other common storage methods are batteries and pumping a working fluid, usually water or air.

But this tech might allow large solar installations away from the grid to make fuel instead of grid electricity. Cost would be key. I think it would be hard to get gasoline under $4/gallon; I seem to recall an estimate of $10/gallon.
Hydrogen, however, requires compression and refrigeration to store whereas gasoline doesnt. Even then, hydrogen is still difficult to store , because it tends to more readily leak from hoses, pipe fittings, due to its small molecular size. It seems theres always tradeoffs.
 
Reactions: William Gaatjes
May 11, 2008
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Hydrogen, however, requires compression and refrigeration to store whereas gasoline doesnt. Even then, hydrogen is still difficult to store , because it tends to more readily leak from hoses, pipe fittings, due to its small molecular size. It seems theres always tradeoffs.
It would become even more interesting if it is possible to also make ammonia instead of gasoline. Ammonia used as hydrogen carrier .
 

[DHT]Osiris

Lifer
Dec 15, 2015
16,979
16,094
146
Barring some unexpected efficiencies or novel uses of gasoline beyond burning it, I really only see this as useful in extremely isolated environments that really need gasoline rather than electricity (isolated groups living in middle eastern mountains that drive Toyotas come to mind...). Otherwise you'd be better off just putting the power into batteries, unless I'm missing something.

Good way to get more gasoline after we empty all the oil fields, I guess.
 
Nov 17, 2019
13,202
7,846
136
Internal combustion engines don't run on batteries. Still don't know any kind of cost estimate for this kind of contraption (which probably will never exist), but I can see if for some people who don't want to replace the dozen or so gas machines they might have.
 

PowerEngineer

Diamond Member
Oct 22, 2001
3,598
774
136
Barring some unexpected efficiencies or novel uses of gasoline beyond burning it, I really only see this as useful in extremely isolated environments that really need gasoline rather than electricity (isolated groups living in middle eastern mountains that drive Toyotas come to mind...). Otherwise you'd be better off just putting the power into batteries, unless I'm missing something.

Good way to get more gasoline after we empty all the oil fields, I guess.

I agree with you and dullard.

The basic issue is that combustion converts only about a third of the energy stored in the fuel into usable work. And this is true regardless of the fuel used. On the other hand, conversion of battery-stored electricity into usable work is upwards of 95% efficient. This means that an ICE car using so-called renewable fuels will only travel a third as far as an electric car can by more directly using the same amount of renewably produced electricity. And that's using the overly generous assumption that the process for producing the renewable fuel is 100% efficient. With the limited exception of hydro reservoirs, batteries are far and away the best method available today for storing renewable energy for use later. Right now renewable fuels only make sense from an energy efficiency standpoint is in applications where battery weight is an overriding factor (e.g. airplanes).

My two cents...
 
Reactions: Ken g6

Chaotic42

Lifer
Jun 15, 2001
34,482
1,662
126
I'm not seeing much info here, so doing a little napkin math at the end of the day. Please obliterate my argument 90s internet style if you're in the mood:

The "octane" from "octane rating" is iso-octane which is 2,2,4-Trimethylpentane or C8H18, which has an enthalpy of formation of -258KJ per mole. They say up to 10kg CO2 per day, which is 227.25 moles, which means if carbon is our limiting reagent, we can get 227.25/8 = 28.4 moles of iso-octane. We'd need 9/8 = 1.25 times as much hydrogen as carbon, so 255.66 moles of hydrogen gas. To get this we'd presumably have to get it from water. To break water into O and H2 costs 285.3 KJ/mole.

The energy to break CO2 into C and O2 is 393.5 KJ/mol, which in a perfect world means to break apart the CO2 we'd need:
Code:
(227.25 mol * 393.5 KJ/mol) = 24.8396875 kilowatt hours

To dehumidify the water with its latent heat of vaporization at 44KJ/mol :
Code:
(255.66 mol * 44 KJ/mol) = 3.12473333 kilowatt hours

To break the water:
Code:
(255.66 mol * 285.3 KJ/mol) = 20.261055 kilowatt hours

and to form the iso-octane we'd generate:
Code:
(28.4 moles * -258 KJ/mol) = -2.03533333 kilowatt hours

So in a super-perfect world, to turn CO2 and moist air into just iso-octane we'd need:
Code:
24.8396875 + 3.12473333 + 20.261055 = 48.22547583 kWH

48.23 kWh. A 400W Silfab solar panel weighs 47 pounds and has an area of 21.4 square feet (https://www.solarelectricsupply.com/silfab-sil-400-hc-plus-400w-solar-panel), which will give about 2kWh per day, so we'd need 25 of them which would be 1,175 pounds and take up 535 square feet. They seem to be around $300 each, so you're looking at $7,500 for the panels alone. Call it $10,000 for the power package.

Of course... the real world isn't ideal. You need to capture the CO2 which is about 65KJ/mole in an ideal situation, which more than doubles our power usage, so maybe $20,000 for the power package and 1100 square feet of roof. Then you need to add in the actual moving parts to do this, the structure, the installation, the transport, the profit, etc. Neat. Maybe $75K per unit? You'd also presumably have to treat the iso-octane to make it usable and you'd get... 4.69 liters.

Let's say you cut that for free down to 87 octane. You'd get 5.4 liters of gasoline per day. At $4/gallon you'd get $5.70 worth of gasoline per day. That's 13,166 days to break even in our fairy tale world. Double neat.
 

[DHT]Osiris

Lifer
Dec 15, 2015
16,979
16,094
146
I agree with you and dullard.

The basic issue is that combustion converts only about a third of the energy stored in the fuel into usable work. And this is true regardless of the fuel used. On the other hand, conversion of battery-stored electricity into usable work is upwards of 95% efficient. This means that an ICE car using so-called renewable fuels will only travel a third as far as an electric car can by more directly using the same amount of renewably produced electricity. And that's using the overly generous assumption that the process for producing the renewable fuel is 100% efficient. With the limited exception of hydro reservoirs, batteries are far and away the best method available today for storing renewable energy for use later. Right now renewable fuels only make sense from an energy efficiency standpoint is in applications where battery weight is an overriding factor (e.g. airplanes).

My two cents...
*flywheels*
Am I a joke to you?
 

Josh128

Senior member
Oct 14, 2022
942
1,423
106
A gallon of gas contains 33.7kwh of energy so even with 100% efficiency you need at least that much sunlight.

Most solar panels around 20-25% efficient at maximums so you really need 4-5 times as much sunlight.

Then you’ve got whatever efficiency this process has for converting CO2 back to a hydrocarbon fuel. So assuming ~30% efficient conversion process,( but who knows - the link doesn’t have any info), and 25% efficient solar array you need about 250kwh of solar energy/ gallon.

If you don’t need the storage of a hydrocarbon fuel directly charging a battery would be much more efficient.

The difference in EVs vs ICE is fascinating from an energy standpoint.

You are correct. EVs are just more efficient. Mine averages 4miles / kWh while my sons Corolla averages ~ 34 mpg or 1mile / kWh. Pretty much any EV is going to be 4 times or more efficient than its ICE counterpart for a given body style. (Sedan vs sedan pick up vs pickup etc)

My battery which holds 82kwh is equivalent to the energy in 2.4 gallons of gas while my sons tank holds 13 gallons. So he can go well over 400 miles on a tank and I struggle to get much over 300 on a battery.

The fastest chargers top out at 350KW which is 5.8kwh / minute while a fast gas pump can do 10 gallons / minute or the equivalent of 337 kWh / minute almost 60 times faster but the EV tank is 5-6 times smaller.
Good post. It's no surprise why they dont give the power and dimensions of the solar array needed to power their pilot unit. That said, using a wind turbine, or even better, hydro-electric power generation, is much more viable.

A single 80 meter, 1.5MW commercial wind turbine running full tilt can make up to ~36MWh in a day, so if we figure ballpark 45KWh per gallon of gasoline (~75% production efficiency), you are looking at most at producing quite a few gallons of fuel per day. Thats considering a perfect turbine with perfect wind for 24 hours. Im sure the actual number can be halved or even quartered for an average daily, but it still seems pretty high.
 

Red Squirrel

No Lifer
May 24, 2003
69,976
13,475
126
www.anyf.ca
Flywheels are more for short term energy storage, I can see this machine being viable for long term, ex: seasonal. You generate a bunch of excess energy on a day where there's lot of sun or wind, then can dip into that stored energy weeks or even months later when needed. Would be cool if such machine ever became available to consumers as it would be a great way to have a bit more self reliance to have fuel for the generator in winter. Ideally you'd have an EV and everything is electric, you would only use fuel as a form of energy storage when solar/wind is over producing, and use it when it's not producing enough. Run a generator for a few hours to top up the battery. The round trip efficiency of it is not all that great but it's "free" energy.
 
May 11, 2008
21,986
1,356
126
Flywheels are more for short term energy storage, I can see this machine being viable for long term, ex: seasonal. You generate a bunch of excess energy on a day where there's lot of sun or wind, then can dip into that stored energy weeks or even months later when needed. Would be cool if such machine ever became available to consumers as it would be a great way to have a bit more self reliance to have fuel for the generator in winter. Ideally you'd have an EV and everything is electric, you would only use fuel as a form of energy storage when solar/wind is over producing, and use it when it's not producing enough. Run a generator for a few hours to top up the battery. The round trip efficiency of it is not all that great but it's "free" energy.
I wonder if there ever have been developed, double piston ICE generators running at peak efficiency. It seems to be, Innengine has done so, according to their site.
ICE (Internal Combustion Engine) will never match Electromotors. That is because of the crazy efficiency and characteristics of electromotors in comparison to ICE.

But i think that for generators with high efficiency double piston engines would be great for ICE driven generators.
When i watch these websites and youtube documentaries , that gallon of gasoline a day becomes much more positive with ICE engines that can reach over 50% efficiency it seems.

Maybe Chaotic42 has some real life numbers ?





edit: I added some text. Forgot the whole subject. double piston ICE driven generators.
 
Last edited:
May 11, 2008
21,986
1,356
126
I do not want to derail the thread,
These E-rex and rex-B engines from INNengine just are ICE engines that would do very well with the gasoline out of air device. Great for generators. And UAV drones and manned drones it seems.

 
Last edited:

PowerEngineer

Diamond Member
Oct 22, 2001
3,598
774
136
*flywheels*
Am I a joke to you?

I wouldn't want you to think that you are a joke to me, but I have yet to see any mechanical energy storage schemes that have proved workable for sizeable amounts of power (> 1000 MW-hr) over extended periods of time (days or weeks). I will think of these as something like a bad joke until I see a mechanical storage scheme demonstrate this level of performance.


Yes, flywheel energy storage is a "thing". And it has been touted as a "thing" for a very long time. There are lots of these kinds of "things" that have been touted as being on the verge of widespread practical application for literally decades (like fusion power). Right now these are only used in special circumstances and only store small amounts of energy for short periods of time. However, I would certainly be happy to be surprised by flywheels actually becoming a meaningful "thing" on the power system.

I know! I'm surprised he ignored it as a potential high efficiency storage tool.

Again, there is no shortage of ideas out there for storing energy. And I'll grant you that they all might have some non-zero "potential" to become the best practicable method for efficiently storing renewable energy. Compressed air and superconducting coils are two other methods often mentioned (along with all sorts of different battery technologies). I have no idea which (if any) of these might change today's status quo, but I'm not ready to include these speculative technologies into my thinking until they are demonstrated to work on the kind of scale needed.

Another two cents...
 
Reactions: Ken g6
Dec 10, 2005
27,703
12,157
136
Solar can be stored in numerous ways. The most common options are:
  • Batteries which are self-explanatory. Pretty simple to use. Infinitely and cheaply recyclable when they reach their lifespan after 10+ years. But, quite expensive to build that first battery.
  • Heat: use solar to heat an object then use the heat to produce energy whenever you want. There is hot sand, hot salt, or just store the extra energy in your water heater (which is actually how much of the world uses solar).
  • Potential energy. Often you can move something high and then let gravity lower it producing energy whenever you want. Or there is the age-old flywheel method. Use the solar to spin a flywheel and then slow the flywheel down when you want to use more energy.
The real question is can this do it any more efficiently than the options above.

The average family in the US uses about 2 gallons of gasoline per day. Thus, on ideal days, they'd need 2 of these machines. But, solar isn't flawless. You get days without much solar production. They average about half power over the whole lifespan vs their best days. So, double that and the average family needs 4 of these machines. It is hard to tell from that image in the OP, but it looks like it needs at least four 22 ft^2 solar panels for one machine. Possibly more since the image cuts off. Now we are talking 16+ solar panels for the average family.
What's also missing is that burning gasoline is still throwing pollutants into the air. It isn't just about climate change.
 

WelshBloke

Lifer
Jan 12, 2005
32,569
10,757
136
I'm calling bullshit until they can demonstrate this working while independent testers get to poke around it.
Really sounds like another cold fusion scam.
 
Reactions: Brainonska511

[DHT]Osiris

Lifer
Dec 15, 2015
16,979
16,094
146
I wouldn't want you to think that you are a joke to me, but I have yet to see any mechanical energy storage schemes that have proved workable for sizeable amounts of power (> 1000 MW-hr) over extended periods of time (days or weeks). I will think of these as something like a bad joke until I see a mechanical storage scheme demonstrate this level of performance.
Just messing with you, flywheels don't get the attention they deserve imo. They'd work great at a small scale as a brownout gap.
 

dullard

Elite Member
May 21, 2001
25,825
4,385
126
I wouldn't want you to think that you are a joke to me, but I have yet to see any mechanical energy storage schemes that have proved workable for sizeable amounts of power (> 1000 MW-hr) over extended periods of time (days or weeks). I will think of these as something like a bad joke until I see a mechanical storage scheme demonstrate this level of performance.
I guess the rest of us don't need a personal 1000 MWhr energy storage system. Remember this discussion is about a personal-use device for up to 1 gallon of gas per day. Which is why my examples were of things like dumping the extra solar power into your water heater.

My solar panels only average 0.79 MWhr per month. So, I guess in >105 years I'll fill your 1000 MWhr personal energy storage once.
 
Last edited:

Josh128

Senior member
Oct 14, 2022
942
1,423
106
I wouldn't want you to think that you are a joke to me, but I have yet to see any mechanical energy storage schemes that have proved workable for sizeable amounts of power (> 1000 MW-hr) over extended periods of time (days or weeks). I will think of these as something like a bad joke until I see a mechanical storage scheme demonstrate this level of performance.



Yes, flywheel energy storage is a "thing". And it has been touted as a "thing" for a very long time. There are lots of these kinds of "things" that have been touted as being on the verge of widespread practical application for literally decades (like fusion power). Right now these are only used in special circumstances and only store small amounts of energy for short periods of time. However, I would certainly be happy to be surprised by flywheels actually becoming a meaningful "thing" on the power system.



Again, there is no shortage of ideas out there for storing energy. And I'll grant you that they all might have some non-zero "potential" to become the best practicable method for efficiently storing renewable energy. Compressed air and superconducting coils are two other methods often mentioned (along with all sorts of different battery technologies). I have no idea which (if any) of these might change today's status quo, but I'm not ready to include these speculative technologies into my thinking until they are demonstrated to work on the kind of scale needed.

Another two cents...
You ever heard of the "hot pile of sand / sandbed" method of storing energy? One of the more simple yet pretty intuitive ideas out there. There is also the idea of adding carbon black to home/building foundation concrete slabs to make "supercapacitors" to store a lot of energy.




 
Last edited:

PowerEngineer

Diamond Member
Oct 22, 2001
3,598
774
136
I guess the rest of us don't need a personal 1000 MWhr energy storage system. Remember this discussion is about a personal-use device for up to 1 gallon of gas per day. Which is why my examples were of things like dumping the extra solar power into your water heater.

My solar panels only average 0.79 MWhr per month. So, I guess in >105 years I'll fill your 1000 MWhr personal energy storage once.

You are right in saying that individual households do not need storage on the scale that I am talking about, but we certainly do if we as a society want to replace fossil fuels with wind and solar energy. I plead guilty to thinking about the problem of energy storage at this societal level. (And I am making the assumption that large-scale approaches will prove to be more efficient than widespread application of small-scale approaches.) FWIW I also harbor (perhaps unfounded) concerns over the possible abrupt release of energy from malfunctioning storage devices in home settings.
 

Paratus

Lifer
Jun 4, 2004
17,481
15,461
146
You are right in saying that individual households do not need storage on the scale that I am talking about, but we certainly do if we as a society want to replace fossil fuels with wind and solar energy. I plead guilty to thinking about the problem of energy storage at this societal level. (And I am making the assumption that large-scale approaches will prove to be more efficient than widespread application of small-scale approaches.) FWIW I also harbor (perhaps unfounded) concerns over the possible abrupt release of energy from malfunctioning storage devices in home settings.

Passively propagation resistant lithium ion batteries is what you want for home storage.


You want the individual cells to vent out the top of the cell away from their neighbors. You also have to design a plenum that can safely exhaust the effluent without redistributing it onto the neighboring cells causing them to short.

That’s how you deal with the biggest risk for home battery storage - thermal runaway.
 

gorobei

Diamond Member
Jan 7, 2007
3,947
1,430
136
making hydrocarbons from air is a thing you can do, but it isnt efficient and will always be too expensive outside of niche requirements.

the US navy successfully demonstrated generating jet fuel from seawater something like 20 years ago, it was relevant for aircraft carriers in the uncertainty of the invasion of iraq and afghanistan and potential hostility from some opec members driving up oil costs. so the tech is fine for that emergency usage case but will never be feasible for commercial/residential use.

you would never bother with these as the input costs are too high absent some miracle catalyst that reduces the need for heat/electricity to extract the hydrogen. if all you want is greener hydrocarbons, then bio-diesel from algae is a better place to spend on research and scaling since they already generate the complex HC chains and you get livestock fodder from the leftover components after oil extraction.


for everyone talking about storage solutions:
solar/wind/etc generation are good on carbon release and pretty good on generation efficiency, but because they arent on demand adhoc their most productive hours dont align with consumer demand times. so the rates the grid will pay for their output isnt great and most operators tend to run well below their possible output with windmills and solar panels going idle. storage can help by banking the most power when solar/wind are most productive and selling it later.

but the conversion costs for turning the electricity into potential energy (heat/momentum/altitude) and then converting back when the grid demands it means you are losing a lot of the efficiency of green power. as storage solutions get better/bigger and wind/solar get more efficient you can eventually beat out fossil fuel or at least be at total cost parity, but with the initial infrastructure costs to build the storage solutions the energy companies will always revert back to established/cheap/mature oil. hydro and geothermal are only able to compete with oil because they are on demand.
 
Reactions: [DHT]Osiris
May 11, 2008
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About the subject of flaring gas at refineries :
It seems there are solutions available for some time now. Good to know.

Small excerpt from text :
"
With the implementation of the latest EPA NSPS Ja flare regulations, refineries are under tremendous pressure to dramatically reduce overall plant emissions to avoid costly consequences. Zeeco offers the industry’s most economical solution to transition refinery flares to a clean, energy-efficient flare gas recovery process that also creates surprising economic benefits and better bottom lines.

ZEECO® Flare Gas Recovery (FGR) systems meet the strict compliance issues of NSPS Ja and help refiners recoup their financial investment in the shortest amount of time. Our FGR systems work with your existing flare to achieve near-zero flaring while recovering valuable waste gas that can be reused as fuel or feedstock.

Near-zero flaring reduces fuel gas consumption; reduces flaring light, noise, and odor; reduces steam consumption; lengthens flare tip life; and builds a more positive company image. In other words, ZEECO FGR systems deliver an exponential advantage that literally pays for itself.
"

Small excerpt from text :
"
The first-ever EU rules to curb methane emissions from the energy sector in Europe and across the globe have become legislation today. This adoption marks another step in the implementation of the European Green Deal and REPowerEU. It shows Europe’s determination to tackle harmful emissions at home and internationally.

The new regulation obliges the fossil gas, oil and coal industry in Europe to measure, monitor, report and verify their methane emissions according to the highest monitoring standards, and to take action to reduce them. It requires EU gas, oil and coal operators to stop avoidable and routine flaring and to reduce flaring and venting to situations such as emergencies, technical malfunctions or when it is necessary for safety reasons.

With Europe importing a large part of the fossil energy it consumes, the regulation will also help to reduce methane emissions from imported fossil fuels. The regulation will progressively introduce more stringent requirements to ensure that exporters gradually apply the same monitoring, reporting and verification obligations as EU operators.

The new rules require the Commission to put in place a monitoring tool on global methane emitters to provide information, based on satellite data, on the magnitude, occurrence and location of high methane-emitting sources occurring within or outside the EU.

The Commission will also set up a rapid alert mechanism for 'super-emitting' events, namely incidents where facilities, equipment or infrastructure emit very high rates of methane. The mechanism will act as an early warning system to detect super emitting events and alert the EU or non-EU country in order for action to be taken to stop or prevent them.
"
 
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